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亚熔盐清洁化工冶金课题组是一支年轻、充满活力的科研创新团队。亚熔盐课题组面向我国化工冶金工业中现有传统工艺资源能源利用率低、环境污染严重、急待转型升级的重大需求，以亚熔盐非常规介质冶金过程化学场强化为核心，开展两性金属矿物资源亚熔盐清洁化工冶金的基础和应用研究，突破资源亚熔盐非常规介质高效反应分离及产品转化关键技术，建立亚熔盐非常规介质的全新化学体系和集成技术，大幅度提高资源和能源利用率，从源头削减废弃物，实现资源高效、清洁和综合利用。
课题组由张懿院士担任学术指导，郑诗礼研究员担任组长，课题组现有研究员2人，副研2人，助研3人，项目人员6人，博士研究生7人，硕士研究生9人，已形成一支多学科交叉结合、梯队合理的研究队伍。课题组以从国外引进的优秀人才以及从事本领域研究有博士学位的年轻研究人员为主体，有较强的创新突破能力，能完成基础-应用-工程开发全过程研究。
课题组重点从事亚熔盐非常规介质清洁化工冶金应用基础研究以及钒、铬、铝、钽/铌的亚熔盐清洁工艺研究。在亚熔盐非常规介质基础研究方面，通过相平衡与相图构建、反应热力学评价与优化、及热力学模型建立与相平衡预测等研究，提出了亚熔盐体系高效节能相分离方法，并发现了水分压的动力学调控作用，提出了亚熔盐反应过程调控规律。在亚熔盐非常规介质全新化学理论体系构建方面，电化学和分子动力学研究证实亚熔盐介质中产生的高活性氧负离子在处理难分解两性金属矿物过程中起关键作用，阐明了亚熔盐非常规介质催化活化矿物分解的多相反应机理，为亚熔盐介质强化矿物分解提供了重要的理论依据。
在万吨级铬盐清洁生产技术研发中，突破强碱体系多元多相分离难点，建立了伴生组分组合相分离方法，完成万吨级铬盐清洁生产示范工程相分离工序的产业化实施，获2005年度国家技术发明二等奖。在钒钛磁铁矿钒铬资源利用方面，与河北钢铁股份有限公司承德分公司合作开发亚熔盐法钒渣钒铬高效提取分离的清洁生产技术，在反应温度比传统工艺降低400℃条件下，钒渣中钒回收率较传统工艺提高15%以上，铬回收率由不足5%提高至80%以上，目前已完成公斤级验收，正在进行千吨级示范工程的建设，该项目同时获得国家863、国家自然科学基金重大项目、院地合作等资金的支持。在粉煤灰综合利用方面，研发了亚熔盐法粉煤灰综合利用技术，可实现氧化铝回收率大于90%，硅产品用于制备新型建筑材料，与中煤集团金海洋北京化工技术研究院合作建设万吨级示范，目前正处扩大试验阶段。在难分解低品位钽铌矿利用方面，建立了外场与介质协同强化的亚熔盐法钽铌清洁冶金工艺，对难处理钽铌矿的分解率由现行工艺的不足85%提高至95%，并可实现氟污染源头削减，该项目获国家863课题及国家自然科学基金面上项目支持，863结题验收为优，获滚动支持。针对我国大宗高碱拜耳法赤泥，建立了亚熔盐法氧化铝高效提取与尾渣综合利用新技术，可实现氧化铝回收率大于80%，尾渣碱含量小于1%，易于实现规模化综合利用，行业和企业极为关注。
目前，除了将已有技术进行工程放大与产业化推广外，课题组正在不断加快先进、前沿技术的突破，包括两性金属产品电化学短流程制备、NaOH/KOH反应萃取分离技术、锂离子电池中高性能含钒电极材料研发等，以为课题组的可持续发展提供重要技术保障。
课题组还积极进行研发平台与基地建设，与承钢公司合作共建了“钒钛资源高效清洁利用与产品工程”联合实验室，是中国钢铁工业协会钒业分会理事单位代表。2011年7月，课题组加入了钒钛资源综合利用产业技术创新战略联盟。
课题组由张懿院士担任学术指导，郑诗礼研究员担任组长，课题组现有研究员2人，副研2人，助研3人，项目人员6人，博士研究生7人，硕士研究生9人，已形成一支多学科交叉结合、梯队合理的研究队伍。课题组以从国外引进的优秀人才以及从事本领域研究有博士学位的年轻研究人员为主体，有较强的创新突破能力，能完成基础-应用-工程开发全过程研究。
课题组重点从事亚熔盐非常规介质清洁化工冶金应用基础研究以及钒、铬、铝、钽/铌的亚熔盐清洁工艺研究。在亚熔盐非常规介质基础研究方面，通过相平衡与相图构建、反应热力学评价与优化、及热力学模型建立与相平衡预测等研究，提出了亚熔盐体系高效节能相分离方法，并发现了水分压的动力学调控作用，提出了亚熔盐反应过程调控规律。在亚熔盐非常规介质全新化学理论体系构建方面，电化学和分子动力学研究证实亚熔盐介质中产生的高活性氧负离子在处理难分解两性金属矿物过程中起关键作用，阐明了亚熔盐非常规介质催化活化矿物分解的多相反应机理，为亚熔盐介质强化矿物分解提供了重要的理论依据。
在万吨级铬盐清洁生产技术研发中，突破强碱体系多元多相分离难点，建立了伴生组分组合相分离方法，完成万吨级铬盐清洁生产示范工程相分离工序的产业化实施，获2005年度国家技术发明二等奖。在钒钛磁铁矿钒铬资源利用方面，与河北钢铁股份有限公司承德分公司合作开发亚熔盐法钒渣钒铬高效提取分离的清洁生产技术，在反应温度比传统工艺降低400℃条件下，钒渣中钒回收率较传统工艺提高15%以上，铬回收率由不足5%提高至80%以上，目前已完成公斤级验收，正在进行千吨级示范工程的建设，该项目同时获得国家863、国家自然科学基金重大项目、院地合作等资金的支持。在粉煤灰综合利用方面，研发了亚熔盐法粉煤灰综合利用技术，可实现氧化铝回收率大于90%，硅产品用于制备新型建筑材料，与中煤集团金海洋北京化工技术研究院合作建设万吨级示范，目前正处扩大试验阶段。在难分解低品位钽铌矿利用方面，建立了外场与介质协同强化的亚熔盐法钽铌清洁冶金工艺，对难处理钽铌矿的分解率由现行工艺的不足85%提高至95%，并可实现氟污染源头削减，该项目获国家863课题及国家自然科学基金面上项目支持，863结题验收为优，获滚动支持。针对我国大宗高碱拜耳法赤泥，建立了亚熔盐法氧化铝高效提取与尾渣综合利用新技术，可实现氧化铝回收率大于80%，尾渣碱含量小于1%，易于实现规模化综合利用，行业和企业极为关注。
目前，除了将已有技术进行工程放大与产业化推广外，课题组正在不断加快先进、前沿技术的突破，包括两性金属产品电化学短流程制备、NaOH/KOH反应萃取分离技术、锂离子电池中高性能含钒电极材料研发等，以为课题组的可持续发展提供重要技术保障。
课题组还积极进行研发平台与基地建设，与承钢公司合作共建了“钒钛资源高效清洁利用与产品工程”联合实验室，是中国钢铁工业协会钒业分会理事单位代表。2011年7月，课题组加入了钒钛资源综合利用产业技术创新战略联盟。
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